1174725-55-3Relevant articles and documents
Use of catalytic fluoride under neutral conditions for cleaving silicon-oxygen bonds
Dilauro, Anthony M.,Seo, Wanji,Phillips, Scott T.
experimental part, p. 7352 - 7358 (2011/11/06)
This Article describes the development of conditions for cleaving silicon-oxygen bonds using catalytic quantities of fluoride at neutral pH in mixed organic-aqueous solutions that contain buffer. A variety of silicon protecting groups can be removed under these conditions, which show tolerance for acid- and base-sensitive groups. A modified procedure also is presented using catalytic fluoride in anhydrous dimethyl sulfoxide-methanol, which generates primarily volatile silicon byproducts.