117499-83-9

Basic information

• Product Name: {(2,6-diisopropylphenyl)(methoxy(2,2,6,6-tetramethylpiperidino)boryl)amino}dimethoxyarsane
• CAS NO: 117499-83-9
• Molecular Weight: 494.358
• Mol File: 117499-83-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {(2,6-diisopropylphenyl)(methoxy(2,2,6,6-tetramethylpiperidino)boryl)amino}dimethoxyarsane(CAS DataBase Reference)
• NIST Chemistry Reference: {(2,6-diisopropylphenyl)(methoxy(2,2,6,6-tetramethylpiperidino)boryl)amino}dimethoxyarsane(117499-83-9)
• EPA Substance Registry System: {(2,6-diisopropylphenyl)(methoxy(2,2,6,6-tetramethylpiperidino)boryl)amino}dimethoxyarsane(117499-83-9)

Safety Data

• Hazardous Substances Data: 117499-83-9(Hazardous Substances Data)

Upstream product

• 113748-54-2 (2,6-diisopropylphenylimino)(2,2,6,6-tetramethylpiperidino)borane 
• 6596-95-8 trimethylarsenite 

Relevant articles and documents

Contributions to the Chemistry of Boron, 193. - Reactions of Amino-imino-boranes with Organyl, Methoxy, and Dimethylamino Compounds of Phosphorus, Arsenic, and Antimony

The insertion of the EO or EN bond of phosphane, arsane, and stibane derivatives of type E(OMe)3 and E(NMe2)3 into the BN bond of the amino-imino-boranes 5a,b is determined by the Lewis acidity of the EX3 compounds which increases for this series according to E = P a decisive role as demonstrated by a decrease in reactivity for the series PhPCl2 > MePCl2 > iPrPCl2 >> tBuPCl2.Chlorophosphorylation occurs specifically to yield products 7.Aminochlorophosphanes do not react specifically with 5a, but (MeO)2PCl yields the methoxyphosphorylation products 12 and 13. - Keywords: Amino-imino-boranes/ Diaminoboranes, P-, As-, and Sb-substituted/ Insertion reactions