117513-99-2Relevant academic research and scientific papers
Straightforward Route to 2- and 3-Formyl Hex-1- and -2-enopyranosides and Their highly Stereoselective Hetero Diels-Alder Reaction with Ethyl Vinyl Ether
Lopez, J. Cristobal,Lameignere, Eric,Lukacs, Gabor
, p. 514 - 515 (1988)
A straightforward route from D-glucose to conjugated enal and diene pyranoses through a dithiane-based methodology is disclosed; hetero Diels-Alder reaction of the enals with ethyl vinyl ether occurs with high stereoselectivity.
Efficient routes to pyranosidic homologated conjugated enals and dienes from monosaccharides
Lopez,Lameignere,Burnouf,De Los Angeles Laborde,Ghini,Olesker,Lukacs
, p. 7701 - 7722 (2007/10/02)
Three new processes for the obtention of pyranosidic dienes type B, and D and homologated conjugated enals A, have been designed in the context of the preparation of useful chiral building blocks from monosaccharides. Addition of vinylmagnesium bromide on
