117514-01-9

Upstream product

• 117513-98-1 methyl 4,6-O-benzylidene-3-deoxy-3-C-dithianyl-2-O-methanesulfonyl-α-D-altro-hexopyranoside 
• 23103-22-2 methyl 4,6-O-benzylidene-3-cyano-2,3-dideoxy-α-D-erythro-hex-2-eno-pyranoside 
• 3150-16-1 methyl 4,6-O-benzylidene-2,3-anhydro-α-D-mannopyranoside 
• 22551-69-5 methyl-3-cyano-3-deoxy-4,6-O-benzylidene-α-D-altropyranoside 
• 35148-42-6 methyl 4,6-O-benzylidene-3-deoxy-3-C-dithianyl-α-D-altro-hexopyranoside 
• 3150-15-0 methyl 2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside 
• 201230-82-2 carbon monoxide 
• 197570-60-8 Trifluoro-methanesulfonic acid (4aR,6S,8aR)-6-methoxy-2-phenyl-4,4a,6,8a-tetrahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester 

Downstream Products

• 117514-04-2 methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-vinyl-α-D-erythro-hex-2-enopyranoside 

Relevant academic research and scientific papers

An expeditious methodology for the incorporation of unsaturated systems into carbohydrates via an enol triflate

One step synthesis of enal, diane, divinyl ketone and enyne systems on a carbohydrate template via an enol triflate.

Improved synthesis of methyl 4,6-O-benzylidene-3-cyano-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside and methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-formyl-α-D-erythro-hex-2-enopyranos ide

Simple and efficient route to the title compounds by using diethyl aluminium cyanide in benzene for the epoxide ring opening and the electrophilic assistance of LiCIO4 during the isomerization-elimination process.

Efficient routes to pyranosidic homologated conjugated enals and dienes from monosaccharides

Three new processes for the obtention of pyranosidic dienes type B, and D and homologated conjugated enals A, have been designed in the context of the preparation of useful chiral building blocks from monosaccharides. Addition of vinylmagnesium bromide on