117533-77-4

Basic information

• Product Name: b-bromo-c(N),d(N')-{N,N-dimethyl-N'-(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato^(1-)}-a-pyridineplatinum(II)
• CAS NO: 117533-77-4
• Molecular Weight: 589.29
• Mol File: 117533-77-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: b-bromo-c(N),d(N')-{N,N-dimethyl-N'-(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato^(1-)}-a-pyridineplatinum(II)(CAS DataBase Reference)
• NIST Chemistry Reference: b-bromo-c(N),d(N')-{N,N-dimethyl-N'-(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato^(1-)}-a-pyridineplatinum(II)(117533-77-4)
• EPA Substance Registry System: b-bromo-c(N),d(N')-{N,N-dimethyl-N'-(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato^(1-)}-a-pyridineplatinum(II)(117533-77-4)

Safety Data

• Hazardous Substances Data: 117533-77-4(Hazardous Substances Data)

Upstream product

• 110-86-1 pyridine 
• 52241-19-7 (platinum)Br2(N,N-dimethylethane-1,2-diamine) 
• 68558-86-1 thallium(I) pentafluorobenzoate 
• 363-72-4 Pentafluorobenzene 

Relevant articles and documents

Organoamidometallics. II. Decarboxylation Syntheses and Structures of platinum(II) Complexes

The complexes (L = py, X = Cl or Br; L = 2-methylpyridine or 4-methylpyridine, X = Cl) have been prepared by decarboxylation reactions between PtX2(dmen) (dmen = N,N-dimethylethane-1,2-diamine) and thallous pentafluorobenzoate in the appropriate hot pyridine.Other organoamidoplatinum(II) complexes, (R = p-HC6F4, X = I; R = C6F5, X = Cl, Br or I; R = p-MeC6F4, X = Cl; R = p-ClC6F4 or p-BrC6F4, X = I) and (R = p-HC6F4; dmpy = 2,5-dimethylpyridine), have been prepared by analogous decarboxylations between PtX2(dmen), thallous 2,3,5,6-tetrafluorobenzoate, and the corresponding polyfluorobenzene, RF.The mixed halogen complex has been prepared similarly and the crystal structure determined.This shows square-planar stereochemistry with the halogen and pyridine trans to NC6F5 and NMe2 respectively.Comparison of spectroscopic data suggests the other complexes have similar stereochemistry.