117538-88-2Relevant academic research and scientific papers
Cooperative catalysis of primary and tertiary amines immobilized on oxide surfaces for one-pot C-C bond forming reactions
Motokura, Ken,Tada, Mizuki,Iwasawa, Yasuhiro
, p. 9230 - 9235 (2008)
(Chemical Equation Presented) D'you know what amine? Primary and tertiary amines are both immobilized on the same silica-alumina surface by silane-coupling reactions. The resultant silica-alumina-supported double-amines are found to exhibit excellent catalysis for 1,3-dinitroalkane synthesis from various aldehydes with nitromethane. A cooperative catalytic mechanism on the solid surface for this efficient synthesis is proposed.
