1175696-12-4Relevant articles and documents
Diene-yne cyclisation reactions of 1-ethynyl-2-vinyl-3,4- dihydronaphthalenes and 1-ethynyl-2-vinylnaphthalenes
Watanabe, Masataka,Shiine, Kodai,Ldeta, Keiko,Matsumoto, Taisuke,Thiemann, Thies
experimental part, p. 669 - 678 (2009/09/06)
The reaction of 1-ethynyl-2-vinyl-3,4-dihydronaphthalenes and 1-ethynyl-2-vinylnaphthalenes over RuCI2(p-cymene) PPh3 leads to 9,10-dihydrophenanthrenes and phenanthrenes in those cases where the ethynyl group in the substrates carries a terminal proton. When 1-phenylethynyl-2-vinyl-3,4-dihydronaphthalenes or 1-phenylethynyl-2- vinylnaphthalenes are reacted over Pt(PPh3)4, 1-methylene-1H-benz[e]-4,5-dihydroindenes and 1-methylene-1H-benz[e]indenes are formed.