117582-61-3

Basic information

• Product Name: 2-Allyl-3-bromo-5,5-dimethyl-2-cyclohexenone
• CAS NO: 117582-61-3
• Molecular Weight: 243.143
• Mol File: 117582-61-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Allyl-3-bromo-5,5-dimethyl-2-cyclohexenone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Allyl-3-bromo-5,5-dimethyl-2-cyclohexenone(117582-61-3)
• EPA Substance Registry System: 2-Allyl-3-bromo-5,5-dimethyl-2-cyclohexenone(117582-61-3)

Safety Data

• Hazardous Substances Data: 117582-61-3(Hazardous Substances Data)

Upstream product

• 1131-02-8 2-allyl-5,5-dimethylcyclohexane-1,3-dione 

Relevant articles and documents

Palladium-Catalyzed Inter- and Intramolecular Cross-Coupling Reactions of B-Alkyl-9-borabicyclononane Derivatives with 1-Halo-1-alkenes or Haloarenes. Syntheses of Functionalized Alkenes, Arenes, and Cycloalkenes via a Hydroboration-Coupling Sequence

The cross-coupling reaction of B-alkyl-9-borabicyclononanes (B-R-9-BBN), readily obtainable from alkenes by hydroboration, with 1-halo-1-alkenes or haloarenes in the presence of a catalytic amount of PdCl2(dppf) and bases, such as sodium hydroxide, potassium carbonate, and phosphate, gave the corresponding alkenes or arenes.Because the reaction is tolerant of a variety of functionalities on either coupling partner, stereochemically pure functionalized alkenes and arenes can be obtained under mild conditions.The utility of the reaction was demonstrated by the stereoselective synthesis of 1,5-alkadienes (7 and 8) and the extension of a side chain in a steroid (11).The hydroboration of haloalkadienes (12), followed by the intramolecular cross-coupling, gave a short-step procedure for synthesis of cycloalkenes, benzo-fused cycloalkenes, and exocyclic alkenes (14 and 16).