117591-80-7Relevant academic research and scientific papers
Reactions of caryophyllene, isocaryophyllene, and their epoxy derivatives with acetonitrile under ritter reaction conditions
Yarovaya,Korchagina,Rybalova,Gatilov,Polovinka,Barkhash
, p. 1593 - 1598 (2004)
Acid-catalyzed reactions between acetonitrile and caryophyllene, isocaryophyllene, caryophyllene 4β,5α-epoxide, and isocaryophyllene 4β,5β-epoxide affording optically active amides with a tricyclic skeleton were investigated. 2004 MAIK "Nauka/Interperiodica".
MOLECULAR REARRANGEMENTS OF NEOCLOVENE IN ACIDIC MEDIA. THE EFFECT OF THE NATURE OF THE MEDIUM ON THE PREFERRED DIRECTION IN MULTISTAGE CARBOCATIONIC REARRANGEMENTS
Khomenko, T. M.,Korchagina, D. V.,Gatilov, Yu. V.,Bagrayanskaya, I. Yu.,Rybalova, T. V.,et al.
, p. 493 - 516 (2007/10/02)
In the case of the transformations of neoclovene in media with various acidities it was discovered experimentally and confirmed by molecular-mechanical calculations, that the relative stability of the carbocations and the corresponding olefins varies in t
