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PYRIDAZINES-XXXIX. N-SUBSTITUTED 1,2-DIHYDRO-1,2-DIAZINES FORMED IN HOMOLYTIC ALKOXYCARBONYLATION REACTIONS OF PYRIDAZINES
Gebauer, Martina,Heinisch, Gottfried,Loetsch, Gerhard
, p. 2449 - 2456 (1988)
Pyridazine and C-alkylpyridazines were found to yield N-ethoxycarbonyl-1,2-dihydropyridazines 1 - 6 when subjected to conditions of homolytic ethoxycarbonylation.This is the first example of an attack of a radical at the nitrogen atom of a N-heteroarene in Minisci-type reactions.
