117635-34-4Relevant academic research and scientific papers
Synthesis of palladium nanoparticles using triazolium based ionic liquids: A reusable catalyst for addition of arylboronic acids to nitrostyrenes
Sundararaju, Kavya,Veeraragavan, VijayaKumar,Chidambaram, Ramesh Kumar
, p. 3000 - 3014 (2018)
Formation of stable and small-sized palladium nanoparticles of diameter 9.4 nm was accomplished by a simple heating of Pd(OAc)2 in 1-octyl-1,2,4-triazolium trifluoroacetate ionic liquid under standard atmospheric hydrogen pressure. Palladium na
Deoxycholic acid-derived biaryl phosphites as versatile and enantioselective ligands in the rhodium-catalyzed conjugate addition of arylboronic acids to nitroalkenes
Jumde, Varsha R.,Iuliano, Anna
, p. 3475 - 3483 (2013)
A highly enantioselective conjugate addition of arylboronic acids to cyclic as well as acyclic aromatic and aliphatic nitroalkenes is presented. The rhodium complexes obtained from deoxycholic acid-derived binaphthyl and flexible biphenyl phosphites showed good activity as well as very high enantioselectivity (ee up to 99%) in the conjugated addition even in the presence of challenging substrates such as 1-nitrocyclohexene or aliphatic acyclic nitroalkenes. Copyright
Synthesis of 1,1-Diaryl-2,2-dimethoxyethanes
Ashwood, Michael S.,Bell, Lawrence A.,Houghton, Peter G.,Wright, Stanley H. B.
, p. 379 - 381 (2007/10/02)
The 1,4-addition of Grignard reagents to β-nitrostyrene to give 1,1-diaryl-2-nitroethanes and their subsequent conversion via a modified Nef reaction into 1,1-diaryl-2,2-dimethoxyethanes (diarylacetaldehyde dimethyl acetals) is described.The scope of the reaction has been briefly explored and one example demonstrated on a large scale.
