117675-33-9Relevant academic research and scientific papers
PHTHALOCYANINES AND RELATED COMPOUNDS. XXXV. SYNTHESIS AND COORDINATION CHEMISTRY OF SUBSTITUTED MANGANESE PHTHALOCYANINES
Dolotova, O. V.,Bundina, N. I.,Derkacheva, V. M.,Negrimovskii, V. M.,Minin, V. V.,et al.
, p. 1699 - 1708 (2007/10/02)
Derivatives of manganese phthalocyanine substituted on the periphery of the macrocycle fit into a series of the following coordination forms: PcMnIIIX, L->PcMnIII-O-MnIIIPcII, PcMnIILn (X, aniono ligand; L, base; n=1,2), with stability against oxidation-reduction and protolytic transformations essentially dependent on the nature of the substituents.The PcMnIILn forms may exist as electronic isomers, Pc+*MnILn and Pc-MnIIILn, due to close packing on the energy scale of d orbitals of the manganese atom and ? orbitals of the macro ligand.
