1176904-69-0Relevant articles and documents
Functionalized esters as bis-electrophiles in a silicon-induced domino synthesis of annulated carbocycles
Genrich, Florian,Harms, Guido,Schaumann, Ernst,Gjikaj, Mimoza,Adiwidjaja, Gunadi
experimental part, p. 5577 - 5587 (2009/12/03)
The reaction of silyl-substituted carbanion 1b with arene-1,2-dicarboxylates 6, 15 yields indenone derivatives 11, 16 in a domino process involving silyl C→O migration and elimination. However, in a competing pathway, the initial addition of 1b leads to l