1177265-39-2Relevant academic research and scientific papers
A convenient, rapid, and general synthesis of α-oxo thiocyanates using clay supported ammonium thiocyanate
Meshram,Thakur, Pramod B.,Madhu Babu,Bangade, Vikas M.
experimental part, p. 1780 - 1785 (2012/05/04)
A very rapid, convenient, and general method for the synthesis of α-oxo thiocyanates has been described by using clay supported ammonium thiocyanate. The procedure avoids the use of additional catalyst, solvent, aqueous work-up and the yields are high. Moreover, the method is applicable for a variety of aryl, heteroaryl, alkyl α-halo carbonyls, β-keto tosylates, α-halo β-dicarbonyl, α-tosyl, β-dicarbonyl, alkyl halide, and alkyl tosylates.
Acyl-isothiocyanates as efficient thiocyanate transfer reagents
Palsuledesai, Charuta C.,Murru, Siva,Sahoo, Santosh K.,Patel, Bhisma K.
supporting information; experimental part, p. 3382 - 3385 (2009/12/01)
An unprecedented transfer of a thiocyanate (-SCN) group from aroyl/acyl isothiocyanate to alkyl or benzylic bromide is observed in the presence of a tertiary amine. This process is most effective when the bromomethyl proton is less acidic, while the prese
