117747-34-9Relevant academic research and scientific papers
NEW ALKENYLCOBALT(III) COMPLEXES FROM OXIDATIVE DENITROGENATION OF HYDRAZONES BY COBALT SCHIFF BASE COMPLEX-DIOXYGEN COMPLEX
Nishinaga, Akira,Yamazaki, Shigekazu,Matsuura, Teruo
, p. 6309 - 6312 (2007/10/02)
Oxidation of hydrazones of aliphatic ketones by a Co(salen)-dioxygen system in dichloromethane results in oxidative denitrogenation of the hydrazones to give new 1-alkenylcobalt(III) complexes.Treatment of the alkenyl complexes with sodium borohydride gives the corresponding cis-olefins.
