117757-06-9

Basic information

• Product Name: Ethyl 1-Thio-β-D-glucuronide
• Synonyms: Ethyl 1-Thio-β-D-glucuronide See E926800;Ethyl β-D-Thioglucopyranosiduronic Acid
• CAS NO: 117757-06-9
• Molecular Formula: C₈H₁₄O₆S
• Molecular Weight: 238.25816
• Product Categories: Carbohydrates & Derivatives;Sulfur & Selenium Compounds;Carbohydrates & Derivatives, Sulfur & Selenium Compounds
• Mol File: 117757-06-9.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Ethyl 1-Thio-β-D-glucuronide(CAS DataBase Reference)
• NIST Chemistry Reference: Ethyl 1-Thio-β-D-glucuronide(117757-06-9)
• EPA Substance Registry System: Ethyl 1-Thio-β-D-glucuronide(117757-06-9)

Safety Data

• Hazardous Substances Data: 117757-06-9(Hazardous Substances Data)

Usage

Uses

Ethyl 1-Thio-β-D-glucuronide (cas# 117757-06-9) is a compound useful in organic synthesis.

Upstream product

• 99077-83-5 ethyl [methyl(2,3,4-tri-O-acetyl-1-thio-β-D-glucopyranosyl)uronate] 
• 21085-72-3 1-bromo-2,3,4-tri-O-acetyl-α-D-glucuronic acid methyl ester 

Relevant articles and documents

Preparative route to glucuronyl donors bearing temporary protecting group at O-3 via 6,3-lactonisation by Bz2O or Piv2O

Heating of non-substituted β-D-glucopyranuronic acids in the presence of pivalic or benzoic anhydride in DMF gives 4-O-monoacylated or 2,4-di-O-acylated 6,3-lactones that can be easily transformed into corresponding methyl uronates bearing free OH-groups at C-2 and C-3 or C-3 only, respectively. This method was used for preparation of selectively 3-O-protected glucuronyl donors of thioglycoside and trichloracetimidate types.