117874-08-5

Upstream product

• 113730-88-4 C₇H₁₄O₃ 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 119111-19-2 (2R,4aR,8R,8aS)-6-Allyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol 
• 119111-29-4 (R)-Allyl 2,3-Dideoxy-4,6-O-(phenylmethylene)-D-glucopyranoside 
• 19493-09-5 Methylenetriphenylphosphorane 

Downstream Products

• 1092964-78-7 (2R,4S,5R)-4-(but-3-en-1-yl)-2-phenyl-1,3-dioxan-5-yl 3-(2-methyl-1,3-dioxolan-2-yl)propanoate 
• 117956-73-7 (2R,4aS,5S,7aS)-5-Methyl-2-phenyl-hexahydro-cyclopenta[1,3]dioxine 
• 117874-11-0 <2R-(2α,4aβ,5α,7aβ)>-Hexahydro-5-methyl-2-phenylcyclopenta-1,3-dioxin 

Relevant academic research and scientific papers

Harnessing glycal-epoxide rearrangements: The generation of the AB, EF, and IJ rings of adriatoxin

(Chemical Equation Presented) Climbing the ladder: The generation of three bicyclic subunits ofadriatoxin (see structure) was accomplished by using glycal-epoxide rearrangements, glycal-Claisen rearrangements, and C-glycoside-forming reactions.

Stereochemical Control in Hex-5-enyl Radical Cyclizations: From Carbohydrates to Carbocycles. 3

The hex-5-enyl radical cyclization reaction was applied to prepare highly oxygenated cyclopentanoids from aldopyranose sugars.The Wittig reaction of the sugars readily provides hex-5-en-1-ols which were converted to hex-5-enyl radicals via one of the vari