117902-51-9

Upstream product

• 117902-50-8 4,6-O-benzylidene-5a-carba-α-DL-glucopyranose 
• 108-24-7 acetic anhydride 
• 117902-50-8 (1RS,3RS,6RS,8RS,9SR,10SR)-8,9,10-trihydroxy-3-phenyl-2,4-dioxabicyclo<4.4.0>decane 
• 10226-73-0 DL-(1,2,4/3,5)-5-hydroxymethyl-1,2,3,4-cyclohexanetetrol 
• 1125-88-8 benzaldehyde dimethyl acetal 

Downstream Products

• 117902-50-8 (1RS,3RS,6RS,8RS,9SR,10SR)-8,9,10-trihydroxy-3-phenyl-2,4-dioxabicyclo<4.4.0>decane 
• 117902-59-7 Acetic acid (2R,4aR,6R,7S,8S,8aR)-6-acetoxy-7-acetylamino-2-phenyl-hexahydro-benzo[1,3]dioxin-8-yl ester 
• 117902-59-7 (1RS,3RS,6RS,8SR,9SR,10SR)-9-acetamido-8,10-dihydroxy-3-phenyl-2,4-dioxabicyclo<4.4.0>decane 
• 117902-59-7 Acetic acid (2R,4aR,6R,7S,8R,8aR)-6-acetoxy-7-acetylamino-2-phenyl-hexahydro-benzo[1,3]dioxin-8-yl ester 
• 117902-57-5 (1RS,3RS,6RS,8RS,9SR,10SR)-8,10-dihydroxy-9-nitro-3-phenyl-2,4-dioxabicyclo<4.4.0>decane 
• 117902-57-5 (1RS,3RS,6RS,8RS,9SR,10RS)-8,10-dihydroxy-9-nitro-3-phenyl-2,4-dioxabicyclo<4.4.0>decane 
• 117902-58-6 (1RS,3RS,6RS,8RS,9SR,10RS)-9-acetamido-8,10-dihydroxy-3-phenyl-2,4-dioxabicyclo<4.4.0>decane 
• 117902-58-6 N-((2R,4aR,6S,7S,8S,8aR)-6,8-Dihydroxy-2-phenyl-hexahydro-benzo[1,3]dioxin-7-yl)-acetamide 
• 117902-58-6 (1RS,3RS,6RS,8RS,9SR,10SR)-9-acetamido-8,10-dihydroxy-3-phenyl-2,4-dioxabicyclo<4.4.0>decane 
• 117902-60-0 Methanesulfonic acid (2R,4aR,6R,7S,8R,8aR)-7-acetylamino-6-methanesulfonyloxy-2-phenyl-hexahydro-benzo[1,3]dioxin-8-yl ester 
• 117938-24-6 (2R,4aR,6R,7S,8S,8aR)-6,7,8-Tris-benzyloxy-2-phenyl-hexahydro-benzo[1,3]dioxine 
• 117902-61-1 Methanesulfonic acid (2S,4aS,6S,7S,8R,8aS)-7-acetylamino-8-hydroxy-2-phenyl-hexahydro-benzo[1,3]dioxin-6-yl ester 

Relevant academic research and scientific papers

Synthesis of pseudo-laminarabiose, -cellobiose, and -maltose (D-glucopyranosyl 5a-carba-D- and L-glucopyranoses)

In connection with the synthesis of pseudo-trehalose, disaccharide analogues of naturally occurring disaccharides, having the reducing unit replaced by a carbocyclic ring, have been synthesized as the totally acetylated derivatives. Synthesis of pseudo-α-

SYNTHESIS OF SEVEN PENTA-N,O-ACETYL-PSEUDO-2-AMINO-2-DEOXY-DL-HEXOPYRANOSES

The 1,5-dialdehyde generated through periodate oxidation of 4,7-O-isopropylidene-pseudo-α-DL-galactopyranose (3) undergoes base-catalysed cyclisation with nitromethane to give three crystalline pseudo-2-deoxy-2-nitro-DL-hexopyranose derivatives with the β