117934-75-5Relevant academic research and scientific papers
SYNTHESIS AND CONFORMATIONAL PROPERTIES OF DIIMIDAZOLOMETACYCLOPHANE AND HOMOLOGS
Sasaki, Hideaki,Kitagawa, Tokujiro
, p. 1593 - 1596 (2007/10/02)
Diimidazolometacyclophane (5a), a novel metacyclophane-diene (4) derivative, was synthesized by the ring transformation of the oxazole ring of dioxazolometacyclophane (1a) to imidazole rings.On the basis of proton nuclear magnetic resonance ((1)H-NMR) spectroscopy, the preferred conformation of 5a in solution at room temperature could be assigned as a syn form. - KEYWORDS - cyclophane; metacyclophane; metaparacyclophane; ring transformation; oxazole; imidazole; conformational analysis
