117972-66-4Relevant academic research and scientific papers
HOMO-DIELS-ALDER AND ENE REACTIONS OF PHOSPHAALKYNES
Annen, Ulrich,Regitz, Manfred
, p. 1681 - 1684 (1988)
Cycloalka-1,3-dienes 1 and 6 react with phosphaalkynes 2 to form the bicyclic systems 3 and 7 containing λ3?2-phosphorus atoms.Products 3 and 7 react with a further equivalent of 2 to furnish the tetracycles 4 and 8 by way of a previously unknown homo-Diels-Alder reaction.The ene reaction 9 + 2 - 10 defines the limits of the cycloaddition process.
