1179825-72-9Relevant academic research and scientific papers
Cobalt(II)-catalyzed oxidative coupling of aromatic tertiary amines with enol silyl ethers leading to β-aminoketone derivatives
Sakai, Norio,Muraoka, Takuya,Matsumoto, Shun,Mutsuro, Akihiro,Ogiwara, Yohei
, p. 343 - 346 (2017)
We demonstrated that a cobalt(II)-TBHP (tert-butyl hydroperoxide) oxidizing system efficiently catalyzes the coupling of aromatic tertiary amines with enol silyl ethers, producing the corresponding β-aminoketones.
CuBr-catalyzed reaction of N,N-dimethylanilines and silyl enol ethers: An alternative route to β-arylamino ketones
Huang, Lehao,Zhang, Xunbin,Zhang, Yuhong
, p. 3730 - 3733 (2011/03/18)
Image Presented A wide range of silyl enol ethers undergo the reactions with N,N-dimethylanilines in the presence of transition metal catalysts under mild conditions to give β-arylamino ketones. In the cases of silyl enol ethers derived from unsymmetrical ketones, regiospecific addition of carbonyl compounds was obtained at the olefinic position of silyl enol ether.
