117984-74-4Relevant academic research and scientific papers
A New and General Synthesis of α-Silyl Carbonyl Compounds by Si-H Insertion from Transition Metal Catalyzed Reactions of Diazo Esters and Diazo Ketones
Bagheri, Vahid,Doyle, Michael P.,Taunton, Jack,Claxton, E. Elizabeth
, p. 6158 - 6160 (2007/10/02)
α-Silyl esters and α-silyl ketones are formed in high yield by Rh2(OAc)4- or Cu(acac)2-catalyzed decomposition of diazo esters and diazo ketones in the presence of organosilanes.
