1180509-85-6Relevant articles and documents
Generalized anomeric effect in gem-diamines: Stereoselective synthesis of α-N-linked disaccharide mimics
Sánchez-Fernández, Elena M.,Rísquez-Cuadro, Rocío,Aguilar-Moncayo, Matilde,García-Moreno, M. Isabel,Mellet, Carmen Ortiz,García Fernández, H. José M.
, p. 3306 - 3309 (2009)
The orbital (negative hyperconjugation) contribution to the generalized anomeric effect is highly increased in bicyclic gem-diamines with a pseudoamide-type endocyclic nitrogen atom, which has been exploited for the stereoselective synthesis of configurat