118068-97-6

Basic information

• Product Name: 5-Methyl-3-(toluene-4-sulfonyl)-hex-5-en-2-one
• Synonyms: 5-Methyl-3-(toluene-4-sulfonyl)-hex-5-en-2-one
• CAS NO: 118068-97-6
• Molecular Weight: 266.361
• Mol File: 118068-97-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 5-Methyl-3-(toluene-4-sulfonyl)-hex-5-en-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Methyl-3-(toluene-4-sulfonyl)-hex-5-en-2-one(118068-97-6)
• EPA Substance Registry System: 5-Methyl-3-(toluene-4-sulfonyl)-hex-5-en-2-one(118068-97-6)

Safety Data

• Hazardous Substances Data: 118068-97-6(Hazardous Substances Data)

Upstream product

• 5366-49-4 4-toluenesulfonylacetone 
• 85021-17-6 (2-Methyl-allyl)-N-phenyl-formimidat 
• 118068-91-0 C₈H₁₃NO₃ 
• 94514-04-2 3-tert-Butylsulfanyl-2-methyl-propene 

Relevant articles and documents

SYNTHESIS WITH MANGANIC SALTS; Part IV1: FREE RADICAL TROST ALLYLATION

SH2, allylations of various keto compounds with 2-substituted allylic sulfones or sulfides have been efficiently performed using a ternary oxidizing mixture -i.e. manganic acetate, cupric acetate and lead dioxide- in acetic acid.

Allylation of Active Methylene Compounds with Allyl Oxime Carbonates Catalyzed by Pd(0)

Allylation of active methylene compounds catalyzed by a palladium(0)-phosphine system took place highly stereoselectively by employing allyl oxime carbonates as the allylating reagent.