118071-09-3Relevant academic research and scientific papers
A facile new synthesis of aldehyde enamines in high yield and high purity
Fisher,Lee,Klettke
, p. 1541 - 1546 (1994)
Aldehyde enamines were synthesized in excellent yield and purity by reacting an aldehyde with 2 equivalents of a secondary amine in cyclohexane in the presence of 1.5 equivalents of CaH2. Distilled yields ranged from 65%-92%.
Highly chemoselective formation of aldehyde enamines under very mild reaction conditions
Belanger, Guillaume,Dore, Michael,Menard, Frederic,Darsigny, Veronique
, p. 7481 - 7484 (2007/10/03)
Although ketone enamines are widely used in organic synthesis, aldehyde enamines are rarely employed due to the limitations of their preparation using known methods (need for acid or base, excess of amine, and/or elevated temperature). We have successfull
The reactions of the ozonides with secondary amines: An efficient and novel way to prepare tertiary amine from mono- and 1,1-di-substituted alkenes via corresponding ozonides
Hon, Yung-Son,Lu, Ling
, p. 5309 - 5312 (2007/10/02)
The ozonolysis of mono- and 1,1-di-substituted olefins followed by treatment with secondary amines in the presence of 4A, molecular sieves to give the corresponding tertiary amine in high yields. This transformation involved four sequential reactions in the same flask.
Regioselective Incorporation of CO into Enamines by Rhodium-Catalyzed Reaction with a Hydrosilane and CO
Ikeda, Shin-ichi,Chatani, Naoto,Kajikawa, Yasuteru,Ohe, Kouichi,Murai, Shinji
, p. 2 - 4 (2007/10/02)
In the presence of 2, the reaction of enamines with a hydrosilane and carbon monoxide (140 deg C, 50 atm of CO) resulted in regioselective incorporation of CO into the α-carbon atom to give α-(siloxymethylene) amines, which can be easily conver
