118088-03-2Relevant academic research and scientific papers
On the Use of Epoxy Alcohol-Aldol Rearrangement for Stereoselective Construction of Quarternary Carbon Centers
Shimazaki, Masato,Hara, Hisaaki,Suzuki, Keisuke,Tsuchihashi, Gen-ichi
, p. 5891 - 5894 (2007/10/02)
A new method for the construction of quarternary carbon centers is reported, which is based on the Lewis acid-promoted 1,2-rearrangement of β,γ-epoxy alcohols giving α,α-disubstituted aldols stereospecifically in high yields.
