118132-95-9Relevant academic research and scientific papers
TRIETHYL PHOSPHITE IN ORGANIC SYNTHESIS. A FACILE, ONE-POT CONVERSION OF ALCOHOLS INTO AMINES
Zwierzak, Andrzej
, p. 51 - 54 (2007/10/02)
General protocols for converting primary, secondary, and tertiary alcohols into the corresponding primary amines are presented.
IMINOPHOSPHORANE-MEDIATED TRANSFORMATION OF TERTIARY ALCOHOLS INTO t-ALKYLAMINES AND THEIR N-PHOSPHORYLATED DERIVATIVES
Koziara, Anna,Zwierzak, Andrzej
, p. 6513 - 6516 (2007/10/02)
Novel azidation of tertiary alcohols by means of trimetylsilyl azide in the presence of boron trifluoride etherate has been worked out.The Staudinger reaction of crude azides with triethyl phosphite affords the corresponding iminophosphoranes which can be directly transformed into diethyl N-(t-alkyl)phosphoroamidates or t-alkylamine tosylates.
