118159-68-5Relevant articles and documents
Palladium-catalysed coupling reaction of allenic alcohols with aryl- and alkenylboronic acids
Yoshida, Masahiro,Gotou, Takahiro,Ihara, Masataka
, p. 1124 - 1125 (2004)
The direct coupling of aryl- and alkenylboronic acids with allenic alcohols has been achieved using a palladium catalyst to yield various substituted dienes and trienes in high yields.
NUCLEOPHILIC SUBSTITUTION OF α-ALLENIC ALCOHOLS VIA THE MURAHASHI METHOD: 1,3-DIENES SYNTHESIS.
Fan, Changlie,Cazes, Bernard
, p. 1701 - 1704 (2007/10/02)
The alkylation of α-allenic alcohols 1 by the Murahashi procedure leads to 1,3-dienes 4.This process allows the direct nucleophilic substitution of labile or hindered α-allenic alcohols by organolithium reagents.