118171-50-9Relevant articles and documents
Indium(I) bromide-mediated dichlorocyanomethylation of carbonyl compounds. The preparation of 2,2-dichloro-3-hydroxynitriles
Nóbrega,Gon?alves, Simone M.C,Peppe
, p. 4745 - 4746 (2001)
Carbonyl compounds were efficiently transformed into their corresponding 2,2-dichloro-3-hydroxynitrile derivatives by the action of trichloroacetonitrile and indium(I) bromide.
Reductive Addition of Polyhalomethanes and Their Related Compounds to Aldehydes and 1,2-Elimination of the Coupling Products in a Pb/Al Bimetal Redox System
Tanaka, Hideo,Yamashita, Shiro,Yamanoue, Motoi,Torii, Sigeru
, p. 444 - 450 (2007/10/02)
A Pb/Al bimetal system was used to carry out reductive addition of tetrachloromethane, tetrabromomethane, bromotrichloromethane, trichloroacetamide, and trichloroacetonitrile to aldehydes.Subsequent 1,2-elimination of the halogen atom and hydroxyl group from the coupling products was also performed with the Pb/Al bimetal system.The technology was successfully applied to stereocontrolled syntheses of ethyl trans- and cis-3-(2,2-dihaloethenyl)-2,2-dimethylcyclopropanecarboxylates.