118201-72-2Relevant academic research and scientific papers
Chemistry of Silylated Thioketones. Part 2. Cycloaddition Reactions with 1,3-Dienes
Bonini, Bianca F.,Lenzi, Alberto,Maccagnani, Gaetano,Barbaro, Gaetano,Giorgianni, Patrizia,Macciantelly, Dante
, p. 2643 - 2646 (2007/10/02)
Trimethylsilylphenyl- and triphenylsilylphenyl thioketones easily undergo -cycloadditions with cyclic and open chain 1,3-dienes at room temperature to give silylated thiabicycloheptenes and dihydrothiopyrans in very good yields.With cyclopentadiene the reaction produces exclusively the endo-silylated adducts.Sulphur oxidation and desilylation of the adducts were also investigated.
