118206-93-2

Basic information

• Product Name: cis-{Pt(PPh₃)2(dmso)2}(ClO₄)2
• CAS NO: 118206-93-2
• Molecular Weight: 1074.83
• Mol File: 118206-93-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis-{Pt(PPh₃)2(dmso)2}(ClO₄)2(CAS DataBase Reference)
• NIST Chemistry Reference: cis-{Pt(PPh₃)2(dmso)2}(ClO₄)2(118206-93-2)
• EPA Substance Registry System: cis-{Pt(PPh₃)2(dmso)2}(ClO₄)2(118206-93-2)

Safety Data

• Hazardous Substances Data: 118206-93-2(Hazardous Substances Data)

Upstream product

• 10199-34-5 cis-dichlorobis(triphenylphosphine)platinum(II) 
• 67-68-5 dimethyl sulfoxide 

Relevant articles and documents

Hard ligands as donors to soft metals. 4. Cationic bis(solvent) complexes of palladium(II) and platinum(II) containing monodentate tertiary phosphine ligands

A series of palladium(II) and platinum(II) complexes [M(PR3)2(solvent)2](Y)2 (M = Pd, Pt; PR3 = 1/2 Ph2PCH2CH2PPh2, PMePh2, PPh3; solvent = py, dmso, Me2CO; Y - ClO4, PF6) have been isolated and characterized. The dmso ligands are all oxygen-bonded. Acetone is a very weak ligand readily displaced by moisture, olefins, and even perchlorate ions. The catalytic activity of the acetone complexes in the isomerization and hydrogenation of oct-1-ene is described and compared with that of the chloride-bridged dimeric complexes [M2(μ-Cl)2(PR3)4] (ClO4)2 (M = Pd, Pt; PR3 = 1/2 Ph2PCH2CH2PPh2, PMePh2) in acetone solution.