1182178-18-2Relevant articles and documents
Enantiospecific photochemical Norrish/Yang type II reaction of nonbiaryl atropchiral α-oxoamides in solution-axial to point chirality transfer
Ayitou, Anoklase Jean-Luc,Jesuraj, Josepha L.,Barooah, Nilotpal,Ugrinov, Angel,Sivaguru
, p. 11314 - 11315 (2011/03/19)
(Chemical Equation Presented) α-Oxoamides 1 with o-tert-butyl substitution on the N-phenyl moiety were found to be stable axially chiral atropisomers. These axially chiral α-oxoamides undergo enantiospecific photochemical γ-Hydrogen abstraction in CHClsu