118264-44-1Relevant articles and documents
Iron-catalyzed quick homocoupling reaction of aryl or alkynyl Grignard reagents using a phosphonium ionic liquid solvent system
Kude, Keisuke,Hayase, Shuichi,Kawatsura, Motoi,Itoh, Toshiyuki
experimental part, p. 397 - 404 (2012/01/13)
The iron-catalyzed homocoupling reaction of aryl Grignard reagent was completed very quickly when the reaction was carried out in a phosphonium salt ionic liquid solvent system at 0°C for 5 min. Using a similar reaction system, the first example of the iron-catalyzed homocoupling reaction of alkynyl Grignard reagents has also been accomplished using the ionic liquid technology.