1183-21-7Relevant academic research and scientific papers
Multi-Stage Redox Systems Based on Dicationic P-Containing Polycyclic Aromatic Hydrocarbons
Bouit, Pierre-Antoine,Caytan, Elsa,Delouche, Thomas,Hissler, Muriel,Jacquemin, Denis,Le Guennic, Boris,Roisnel, Thierry,Vacher, Antoine
supporting information, (2020/06/25)
We report the straightforward synthesis of unprecedented electron-acceptors based on dicationic P-containing PAHs (Polycyclic Aromatic Hydrocarbons) based on copper mediated radical approach. In these systems, two phosphoniums are connected through various PAHs backbones. The impact of π-extension on both the optical and redox properties is investigated using a joint experimental (UV/Vis absorption, fluorescence and cyclic voltammetry) and theoretical approach (TD-DFT calculations). Finally, (spectro)-electrochemical studies prove that these compounds possess three redox states and EPR studies confirm the in situ formation of an organic radical delocalized on the PAH backbone.
