118374-38-2Relevant academic research and scientific papers
Synthesis of Higher Monosaccharides using Nitrile Oxide-Isoxazoline Chemistry
Paton, R. Michael,Young, Anne A.
, p. 132 - 134 (2007/10/02)
Octose, nonose and decose derivatives 1, 2, 11, 12 and 18-21 have been synthesised by a sequence involving cycloaddition of sugar nitrile oxides to sugar alkenes, and reductive hydrolytic cleavage of the resulting 2-isoxazolines.
Cycloaddition of nitrile oxides to 3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-α-D-ribo-hex-5-enofuranose
Blake, Alexander J.,Gould, Robert O.,McGhie, Karen E.,Paton, R. Michael,Reed, David,et al.
, p. 461 - 474 (2007/10/02)
Benzonitrile oxide and ethoxycarbonylformonitrile oxide cyclo-added to the title compound to afford a mixture of 3-substituted (phenyl or ethoxycarbonyl)(5R)- (6) and (5S)-5-(3-O-benzyl-1,2-O-isopropylidene-α-D-ribo-tetrofuranos-4-yl)-2-isoxazoline (7).Th
Face Selectivity of the Nitrile Oxide Cycloaddition to Unsaturated Sugars
Amici, De Marco
, p. 793 - 798 (2007/10/02)
Nitrile oxides cycloadd to unsaturated sugars 1a-h, to give the anti adduct with 73.5-96.8percent ?-facial stereoselectivity.The highest values of face selectivity were observed with dipolarophiles bearing an ether group in the homoallylic position.This f
