118396-58-0Relevant academic research and scientific papers
Stereoselective Glycosylation Reactions
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Paragraph 0079-0081, (2014/10/16)
Disclosed is a method for selective synthesis of 1,2-cis-α-linked glycosides which does not require the use of the specialized protecting group patterns normally employed to control diastereoselectivity. Thioglycoside acceptors can be used, permitting ite
Bromodimethylsulfonium bromide-silver triflate: A new powerful promoter system for the activation of thioglycosides
Xiong, De-Cai,Zhang, Li-He,Ye, Xin-Shan
supporting information; experimental part, p. 1696 - 1700 (2009/07/18)
Bromodimethylsulfonium bromide (BDMS) in combination with silver triflate provides a very efficient thiophilic promoter system, capable of activating both "disarmed" and "armed" thioglycosides for glycosidic bond formation. The usefulness of this new prom
