1184110-29-9Relevant articles and documents
Synthesis and crystal structure of 1-(4-fluorophenyl)-and 1-(4-dimethylamino)phenylgermatranes
Lukevics,Ignatovich,Shul'ga,Belyakov
, p. 615 - 620 (2008)
The X-ray crystal structure of 1-(4-fluorophenyl)- and 1-(4- dimethylaminophenyl)germatranes reveals that the germanium atom is pentacoordinated and adopts a trigonal bipyramidal geometry. The fluorophenyl and dimethylaminophenyl groups and the nitrogen atom each occupy an apical position with the transannular N→Ge bond of 2.192(3) and 2.249(3) A; the deviation of the Ge atom from the O(2)-O(8)-O(9) plane is 0.2306(4) and 0.2693(3) A, correspondingly. 2008 Springer Science+Business Media, Inc.