1184182-79-3Relevant academic research and scientific papers
Alternative synthetic path to (-)-adalinine via a SmI2-promoted fragmentation of a 3-oxopyrrolidine derivative
Honda, Toshio,Hisa, Chihiro
, p. 4654 - 4657 (2009)
A novel and stereocontrolled synthetic path to a coccinellid alkaloid, (-)-adalinine, was established by employing the reductive carbon-nitrogen bond cleavage reaction and subsequent recyclization of a 3-oxopyrrolidine derivative with samarium diiodide, a
Application of samarium diiodide-promoted reductive carbon-nitrogen bond cleavage reaction to 3-oxopyrrolidine derivatives: Alternative synthesis of a coccinellid alkaloid, (-)-adalinine
Honda, Toshio,Hisa, Chihiro
body text, p. 1381 - 1406 (2010/10/20)
Samarium diiodide-promoted reductive deamination reaction was applied to 5,5-disubstitued 3-oxopyrrolidines to provide 4,4-disubstituted 4-aminobutan-2-one derivatives, where the carbon-nitrogen bond cleavage took place at the desired position, regioselec
