118436-89-8Relevant academic research and scientific papers
Molecular iodine-promoted N- and C-glycosylation of 1-C-alkyl (or phenyl)-glycopyranoses
Pal, A.P. John,Mallick, Asadulla,Reddy, Y. Suman,Vankar, Yashwant D.
supporting information; experimental part, p. 6334 - 6337 (2011/01/04)
Molecular iodine efficiently promoted the N- and C-glycosylation of hemiketals with Me3SiN3 and Me3SiCN, respectively. Using this method we have prepared diverse functional N- and C-ketosides, which could serve as useful s
Synthesis of the papulacandin C-arylglucosyl spiroketal nucleus
Rosenblum, Stuart B.,Bihovsky, Ron
, p. 2746 - 2748 (2007/10/02)
The enantiomerically pure tricyclic C-arylglucosyl spiroketal nucleus of papulacandin has been synthesized by reaction of an appropriately protected gluconolactone 4 with a metalated derivative of 5-(hydroxymethyl)resorcinol (5). In model studies, alkylli
C-Glycosides. 7. Stereospecific C-Glycosylation of Aromatic and Heterocyclic Rings
Czernecki, S.,Ville, G.
, p. 610 - 612 (2007/10/02)
Stereospecific C-glycosylation of aromatic and heterocyclic rings can be realized by reacting the corresponding organolithium derivatives with benzylated lactones and reducing the so-obtained lactols with triethylsilane in the presence of boron trifluorid
