118486-97-8

Basic information

• Product Name: 1-METHYL-2-(TRIBUTYLSTANNYL)-1H-PYRROLE
• Synonyms: 2-(TRIBUTYLSTANNYL)-1-METHYLPYRROLE;1-METHYL-2-(TRIBUTYLSTANNYL)-1H-PYRROLE;1-METHYL-2-(TRIBUTYLSTANNYL)PYRROLE;(1-METHYLPYRROL-2-YL)TRIBUTYLTIN;1-N-METHYL-2-(TRIBUTYLSTANNYL)-1H-PYRROLE;1-N-METHYL-2-(TRIBUTYLSTANNYL)PYRROLE;N-METHYL-2-(TRIBUTYLSTANNYL)PYRROLE;N-Methyl-2-(tributylstannyl)-1H-pyrrole
• CAS NO: 118486-97-8
• Molecular Formula: C₁₇H₃₃NSn
• Molecular Weight: 370.16
• Product Categories: Organostannes;Pyrrole;Tributylstanny
• Mol File: 118486-97-8.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 376.3 °C at 760 mmHg
• Flash Point: 98 °C
• Appearance: /
• Density: 1.1223 g/mL at 25 °C
• Vapor Pressure: 1.59E-05mmHg at 25°C
• Refractive Index: n20/D 1.5107
• Storage Temp.: ?20°C
• Solubility: Not miscible or difficult to mix.
• PKA: -2.77±0.70(Predicted)
• CAS DataBase Reference: 1-METHYL-2-(TRIBUTYLSTANNYL)-1H-PYRROLE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-METHYL-2-(TRIBUTYLSTANNYL)-1H-PYRROLE(118486-97-8)
• EPA Substance Registry System: 1-METHYL-2-(TRIBUTYLSTANNYL)-1H-PYRROLE(118486-97-8)

Safety Data

• Hazard Codes: T,Xi,N
• Statements: 21-25-36/38-48/23/25-50/53
• Safety Statements: 26-28-36/37-45-60-61
• RIDADR: UN 2788 6.1/PG 2
• WGK Germany: 3
• HazardClass: IRRITANT, AIR SENSITIVE, MOISTUR
• Hazardous Substances Data: 118486-97-8(Hazardous Substances Data)

Usage

Uses

Different sources of media describe the Uses of 118486-97-8 differently. You can refer to the following data:
1. It is employed as intermediate for pharmaceutical.
2. 1-Methyl-2-(tributylstannyl)pyrrole can be used as a reactant to prepare: Bithienylpyrrole derivatives through a Stille coupling reaction with bithienyl bromides in the presence of Pd catalyst. Di(bisthienyl)-o-carborane (DBTC) by reacting with 5,5′-dibromo-o-carboranyl-bisthiophenes using Pd catalyst. DBTC is electropolymerized to produce conducting polymers. Poly(Py-BTz-Py) (2-butyl-4,7-bis(1-methyl-1H-pyrrol-2-yl)-2H-benzo[d][1,2,3]triazole) via Stille coupling reaction. Poly(Py-BTz-Py) can be used as an organic photocatalyst for the formation C-C bond under visible light irradiation.

InChI:InChI=1/C5H6N.3C4H9.Sn/c1-6-4-2-3-5-6;3*1-3-4-2;/h2-4H,1H3;3*1,3-4H2,2H3;/rC17H33NSn/c1-5-8-14-19(15-9-6-2,16-10-7-3)17-12-11-13-18(17)4/h11-13H,5-10,14-16H2,1-4H3

Upstream product

• 96-54-8 N-Methylpyrrole 
• 110-18-9 N,N,N,N,-tetramethylethylenediamine 
• 1461-22-9 tributyltin chloride 

Downstream Products

• 129849-13-4 (6R,7R)-7-tert-Butoxycarbonylamino-3-(1-methyl-1H-pyrrol-2-yl)-8-oxo-5-thia-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid benzhydryl ester 
• 1138450-27-7 5-(1-methyl-1H-pyrrol-2-yl)-1-(3-{(1S,5R)-1-[4-(trifluoromethyl)phenyl]-3-azabicyclo[3.1.0]hex-3-yl}propyl)-2,4(1H,3H)-pyrimidinedione 
• 1021430-23-8 C₃₅H₃₈N₂O₇ 
• 938-37-4 1-methyl-2-phenyl-1H-pyrrole 
• 912762-95-9 2-(3-bromophenyl)-1-methyl-1H-pyrrole 
• 1381847-78-4 2-((4-methoxyphenyl)thio)-1-methyl-1H-pyrrole 
• 1394178-30-3 3-(1-methyl-1H-pyrrol-2-yl)-5-phenyl-4H-1,2,6-thiadiazin-4-one 
• 1239569-15-3 1-methyl-2-(3,4,5-trimethoxyphenyl)pyrrole 
• 1239569-16-4 1-methyl-2-(3,4,5-trihexadecyloxyphenyl)pyrrole 
• 1228392-67-3 3-(1-methyl-1H-pyrrol-2-yl)-1-(phenylsulfonyl)-1H-indole 
• 1047648-89-4 2-[4’-(diphenylamino)phenyl]-1-methylpyrrole 
• 1059597-01-1 (S)-benzyl 1-(1-methyl-1H-pyrrol-2-yl)-1-oxo-3-phenylpropan-2-ylcarbamate 

Relevant articles and documents

PYROVALERONE ANALOGS AND THERAPEUTIC USES THEREOF

New compounds that bind to monoamine transporters are described. The compounds of the present invention can be racemic or pure R-or S-enantiomers. Certain preferred compounds of the present invention have a high selectively dopamine transporter versus the serotonin transporter. Preferred monoamine transporters for the practice of the present invention include the dopamine transporter, the serotonin transporter and the norepinephrine transporter.