118491-97-7

Upstream product

• 33840-74-3 1-(phenylsulfinyl)propan-2-one 
• 64304-94-5 (S)-1-(phenylsulfinyl)-propan-2-one 

Downstream Products

• 118429-63-3 (R_S^*,2S^*)-3-phenylsulfinyl-2,4-tridecanediol 
• 118429-63-3 (S_S^*,2S^*)-3-phenylsulfinyl-2,4-tridecanediol 
• 113317-69-4 (2R,3R)-3-((R)-Benzenesulfinyl)-butan-2-ol 
• 113317-69-4 (2R,3S)-3-((R)-Benzenesulfinyl)-butan-2-ol 
• 118429-64-4 threo-(S_S^*,2S^*)-1-deuterio-1-phenylsulfinyl-2-propanol 
• 118429-64-4 erythro-(S_S^*,2S^*)-1-deuterio-1-phenylsulfinyl-2-propanol 
• 113317-69-4 (2S,3R)-3-((R)-Benzenesulfinyl)-butan-2-ol 
• 113317-69-4 (2S,3S)-3-((R)-Benzenesulfinyl)-butan-2-ol 
• 118429-64-4 erythro-(R_S^*,2S^*)-1-deuterio-1-phenylsulfinyl-2-propanol 
• 118429-64-4 threo-(R_S^*,2S^*)-1-deuterio-1-phenylsulfinyl-2-propanol 

Relevant academic research and scientific papers

Effect of Intramolecular Chelation on Configurational Interconversion of Sulphur-stabilized Carbanions

Sulphur-stabilized carbanions R1R2-SO undergo configurational interconversion, which is affected by intramolecular chelation and the bulk of R.

DIASTEREOSELECTIVE α-ALKYLATION OF β-HYDROXY SULFOXIDES AND ITS APPLICATION TO THE SYNTHESIS OF (+)- AND (-)-DISPARLURE

α-Alkylation of the dianions of β-hydroxy sulfoxides proceeds with high 1,2-asymmetric induction to give threo-α-alkyl-β-hydroxy sulfoxides.The utility of the present reaction was demonstrated in the asymmetric synthesis of (+)- and (-)-cis-7,8-epoxy-2-methyloctadecanes (disparlure).