118526-90-2Relevant academic research and scientific papers
EXPLORATORY STUDY ON α-METALLO SELENONES : Original Syntheses of Oxaspiropentanes.
Krief, A.,Dumont W.,Laboureur, J.L.
, p. 3265 - 3268 (2007/10/02)
Oxaspiropentanes have been obtained from α-metallocyclopropyl phenyl selenones and carbonyl compounds and on reaction of a base with β-hydroxyalkyl cyclopropyl selenones.The original reactivity of other β-hydroxyalkyl selenones is also disclosed.
NOVEL SYNTHESIS OF SELENONES : Application to the Synthesis of Alkyl Cyclopropanecarboxylates.
Krief, A.,Dumont W.,De Mahieu, A.F.
, p. 3269 - 3272 (2007/10/02)
Selenones are prepared by oxidation of selenides by hydrogen peroxide-benzeneseleninic acid.They react with α,β-unsaturated esters and alkylidene malonates in the presence of t-BuOK and produce alkyl cyclopropanecarboxylates.
