1185289-23-9Relevant academic research and scientific papers
A concise and efficient way to synthesize polyenic diones directly from α,β-unsaturated methyl ketones
Gao, Meng,Yin, Guodong,Wang, Zihua,Wu, Yandong,Guo, Cheng,Pan, Yuanjiang,Wu, Anxin
, p. 6047 - 6049 (2009)
A concise and efficient approach to polyenic compounds containing important diketone structural fragments is developed from readily available α,β-unsaturated methyl ketones in the presence of copper(II) oxide, iodine, and dimethyl sulfoxide. This is a new carbon-carbon double bond-forming reaction from two methyl sp3 C-H bonds and an attractive route to introduce the SMe group into the molecule from inexpensive dimethyl sulfoxide. The hypothetic self-sorting tandem reaction mechanism is also proposed in this paper.
