118545-11-2

Upstream product

• 6988-40-5 methyl 2,3-di-O-benzyl-α-D-mannopyranoside 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 118545-17-8 methyl 2,3-di-O-benzyl-4,6-O-<(R)-(1-ethoxycarbonyl)ethylidene>-α-D-mannopyranoside 
• 118545-22-5 methyl 2,3-di-O-benzyl-4,6-O-<(S)-(1-ethoxycarbonyl)ethylidene>-α-D-mannopyranoside 
• 118545-18-9 methyl 2,3-di-O-benzyl-4,6-O-<(S)-(1-benzyloxycarbonyl)ethylidene>-α-D-mannopyranoside 

Relevant academic research and scientific papers

Convenient synthesis of pyruvate acetals of carbohydrates by coupling of trialkylsilylated diols and pyruvates

Hexopyranoside diols, mainly 4,6-diols with α-gluco, β-gluco, α-galacto, β-galacto, and α-manno configurations could be converted effectively (40-74% yields), to the corresponding pyruvate acetals by the coupling of the O-trialkylsilylated, namely, O-TBDM