118578-71-5Relevant articles and documents
4-Phenylbenzylidene benzylamine: a new and convenient reagent for the titration of solutions of lithium alkyls and metal amides
Duhamel, Lucette,Plaquevent, Jean-Christophe
, p. 1 - 3 (1993)
4-Phenylbenzylidene benzylamine is shown to be an excellent reagent for the determination of solutions of lithium alkyls and metal amides.The azaallyl anion produced is deep blue in tetrahydrofuran, and fades to pale yellow via red when titrated with 2-bu
Oxidation of N-benzylaldimines to N-benzylamides by MCPBA and BF3·OEt2
An, Gwang-Il,Rhee, Hakjune
, p. 876 - 878 (2007/10/03)
N-Benzylamides were obtained from the corresponding N-benzylaldimines in high yields. N-Benzylaldimines are readily prepared from the corresponding aldehydes with benzylamine. This procedure involves the oxidation of N-benzylaldimines with MCPBA with BF3·OEt2. In this reaction, the reaction presumably follows an internal hydrogen abstraction to provide only N-benzylamide.
Thermal and Photoisomerisation of Ion Pairs of the 1,3-Diphenyl-2-aza-allyl Carbanion
Young, Ronald N.,Ahmad, Muhanad A.
, p. 35 - 38 (2007/10/02)
Upon irradiation with white light, the predominant conformation of the 1,3-diphenyl-2-aza-allyl carbanion is changed from trans, trans to cis, trans.The kinetics of the reverse dark reaction have been studied.The loose ion pairs with lithium, sodium, and