1186048-28-1

Basic information

• Product Name: 4-(4-Carboxyphenyl)-3-Methylbenzoic acid
• Synonyms: 4-(4-Carboxyphenyl)-3-Methylbenzoic acid;2-METHYL-[1,1-BIPHENYL]-4,4-DICARBOXYLIC ACID
• CAS NO: 1186048-28-1
• Molecular Formula: C15H12O4
• Molecular Weight: 256.25338
• Mol File: 1186048-28-1.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 464.9±40.0 °C(Predicted)
• Appearance: /
• Density: 1.307±0.06 g/cm3(Predicted)
• Storage Temp.: Sealed in dry,Room Temperature
• PKA: 4.14±0.10(Predicted)
• CAS DataBase Reference: 4-(4-Carboxyphenyl)-3-Methylbenzoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(4-Carboxyphenyl)-3-Methylbenzoic acid(1186048-28-1)
• EPA Substance Registry System: 4-(4-Carboxyphenyl)-3-Methylbenzoic acid(1186048-28-1)

Safety Data

• Hazardous Substances Data: 1186048-28-1(Hazardous Substances Data)

Usage

Uses

4-(4-Carboxyphenyl)-3-methylbenzoic Acid was used for preparation of thioether functionalized biphenyldicarboxylate.

Upstream product

• 148547-19-7 4-Bromo-3-methylbenzoic acid methyl ester 
• 99768-12-4 4-methoxycarbonylphenylboronic acid 
• 7697-28-1 4-bromo-3-methylbenzoic acid 
• 14047-29-1 4-carboxyphenylboronic acid 

Relevant articles and documents

Bifunctional Imidazolium-Based Ionic Liquid Decorated UiO-67 Type MOF for Selective CO2 Adsorption and Catalytic Property for CO2 Cycloaddition with Epoxides

A bifunctional robust and highly porous imidazolium-based ionic liquid decorated UiO-67 type MOF (UiO-67-IL, 1) was successfully constructed via solvothermal assembly of the imidazolium-based ligand and Zr(IV) ions. It exhibits a highly selective adsorption for CO2 over CH4 and N2. Furthermore, 1 herein can be used as a highly active heterogeneous catalyst for CO2 cycloaddition with epoxides under atmospheric pressure with or without cocatalyst TBAB (n-Bu4NBr).

Flexible Zirconium Metal-Organic Frameworks as Bioinspired Switchable Catalysts

Flexible metal–organic frameworks (MOFs) are highly desirable in host–guest chemistry owing to their almost unlimited structural/functional diversities and stimuli-responsive pore architectures. Herein, we designed a flexible Zr-MOF system, namely PCN-700 series, for the realization of switchable catalysis in cycloaddition reactions of CO2with epoxides. Their breathing behaviors were studied by successive single-crystal X-ray diffraction analyses. The breathing amplitudes of the PCN-700 series were modulated through pre-functionalization of organic linkers and post-synthetic linker installation. Experiments and molecular simulations confirm that the catalytic activities of the PCN-700 series can be switched on and off upon reversible structural transformation, which is reminiscent of sophisticated biological systems such as allosteric enzymes.

Sulfur-tagged metal-organic frameworks and their post-synthetic oxidation

A series of sulfur-tagged zinc MOFs containing functionalised 4,4′-biphenyldicarboxylate ligands has been prepared: oxidative post-synthetic modification with dimethyldioxirane has converted the sulfide tags into sulfones, leaving the MOF networks intact.