118611-75-9Relevant academic research and scientific papers
Transition Metal Complexes of Unstable Ylides, X. Chemical and Electrochemical Investigations of the Redox Properties of Cyclic Tetracarbonylchromium-Ylide-Chelate-Complexes
Weber, Lothar,Luecke, Ewald,Koelle, Ulrich,Ohst, S.
, p. 892 - 896 (2007/10/02)
Treatment of the ylide chelate complexes (1) with (C5H5)2Fe(+)PF6(-) leads to the organometallic radical cations 2.The oxidation process of 1 is also checked electrochemically by means of cyclovoltammetry, which exhibits a reversibel one electron oxidation between -0.1 and +0.3 V vs.SCE.These potentials are more negative than in any other complex of the general type Cr(CO)4L2 (L e.g. = PR3, CNR). - Chromium Ylide Complex, Chelate Complexes, Redox Properties
