118620-22-7Relevant academic research and scientific papers
TRICYCLIC OXONIUM-DIRECTED ADDITION: REGICHEMISTRY AND STEREOCHEMISTRY OF THE ELECTOPHILIC ADDITIONS TO EPOXY CYCLOALKENOLS.
Alvarez, Eleuterio,Manta, Eduardo,Martin, Julio D.,Rodriguez, Matias L.,Ruiz-Perez, Catalina,Zurita, Dacil
, p. 2097 - 2100 (2007/10/02)
The regio- and stereochemistry of electrophile-promoted transannular ring expansion of cyclo 1,5- and 1,6-epoxyalkenes and cyclo trans-1,5-bisepoxides were studied.The results are rationalized in terms of tricyclic oxonium intermediates showing the directing ability of oxygen substituents in the regio- and stereocontrol observed.
