1186232-10-9Relevant academic research and scientific papers
A theoretical and experimental study of the effects of silyl substituents in enantioselective reactions catalyzed by diphenylprolinol silyl ether
Hayashi, Yujiro,Okamura, Daichi,Yamazaki, Tatsuya,Ameda, Yasuto,Gotoh, Hiroaki,Tsuzuki, Seiji,Uchimaru, Tadafumi,Seebach, Dieter
, p. 17077 - 17088 (2014)
The effect of silyl substituents in diphenylprolinol silyl ether catalysts was investigated. Mechanistically, reactions catalyzed by diphenylprolinol silyl ether can be categorized into three types: two that involve an iminium ion intermediate, such as fo
The organocatalytic addition of bis(arylsulfonyl)methane to α,β-unsaturated aldehydes and the synthesis of optically-enriched 3-methyl-alkanols
Garcia Ruano, Jose Luis,Marcos, Vanesa,Aleman, Jose
supporting information; experimental part, p. 4435 - 4437 (2009/12/29)
An indirect organocatalytic method for the β-methylation of α,β-unsaturated aldehydes that involves the addition of bis(arylsulfonyl)methane catalyzed by prolinol derivatives and further elimination of the chameleonic sulfonyl groups is presented. The Roy
