1186244-63-2Relevant academic research and scientific papers
Organocatalytic asymmetric syn-selective direct aldol reactions in water
Teo, Yong-Chua,Chua, Guan-Leong,Ong, Chin-Yee,Poh, Chai-Yun
, p. 4854 - 4856 (2009)
A practical and convenient organocatalytic strategy is developed to provide a direct route to syn-selective aldol products in the presence of water. The siloxy serine organocatalyst mediates the direct aldol reaction of TBSO-protected hydroxyacetone with
Organocatalytic asymmetric syn-selective direct aldol reaction in ionic liquid
Yong, Fui-Fong,Poh, Chai-Yun,Chua, Guan-Leong,Teo, Yong-Chua
supporting information; experimental part, p. 490 - 492 (2010/09/05)
A practical and recyclable organocatalytic strategy is developed to provide syn-selective aldol products in ionic liquid. The siloxy serine organocatalyst mediates the direct aldol reaction of TBSO-protected hydroxyacetone with a variety of aldehyde to provide the β-hydroxycarbonyl scaffolds in good yields and enantioselectivities up to 94%.
